Monodisperse and isolated microspheres of poly(N-methylaniline) prepared by dispersion polymerization

Monodisperse and isolated microspheres of poly(N-methylaniline) were successfully prepared through chemical polymerization of N-methylaniline by image in adipic acid containing poly(vinylpyrrolidone) (PVP). Mean diameters of the microspheres with smooth surfaces changed from 320 to 100 nm by increasing the reaction temperature from 25 to 75 °C. The concentration of PVP did not affect much the size of microspheres, but the increased PVP concentration led to longer induction times for the onset of dispersion polymerization.