Design of dual functional adsorbent/catalyst system for the control of VOC’s by using metal-loaded hydrophobic Y-zeolites

To design a good combined adsorbent/catalyst dual functional system for the control of the low concentration VOC, both adsorption and catalytic activity test over metal-loaded zeolite HY were carried out. Hydrophobic HY zeolite was selected as a good adsorbent candidate among the tested zeolite adsorbents and extended to the catalyst support material by adding various transition metals. The temperature programmed surface reaction (TPSR) of toluene and methylethylketone (MEK) suggested the silver as the best candidate among the tested transition metals. Temperature programmed reductions (TPR) and O2-temperature programmed desorption (O2-TPD) on Ag/HY catalysts were carried out to explain the nature of active centre of Ag catalyst for the toluene oxidation. Silver oxide species or partially oxidized metallic silver on to the surface of metallic silver phase was proposed as an active redox site during the oxidation reaction.