Title of article
Selective photo-oxidation of various hydrocarbons in the liquid phase over V2O5/Al2O3
Author/Authors
Kentaro Teramura، نويسنده , , Tsunehiro Tanaka، نويسنده , , Tomohiro Hosokawa، نويسنده , , Tai Ohuchi، نويسنده , , Masaya Kani، نويسنده , , Takuzo Funabiki، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
5
From page
205
To page
209
Abstract
More than 0.22 mmol of isolated VO4 species of V2O5/Al2O3 exhibited the highest evolution of the partial oxidation products (alcohol and ketone) in the oxidation of cyclohexane and cyclopentane. The conversion of cyclohexane and the selectivity of the partial oxidation products were achieved to be 0.49% and 85% over 0.8 g of 3.5 wt.% V2O5/Al2O3, respectively, where the K/A ratio was 6.2. In addition, V2O5/Al2O3 can selectively oxidize various hydrocarbons in the liquid phase by the one-step oxygen atom insertion to Csingle bondH bond. The order of priority was tertiary carbon > secondary carbon > primary carbon > benzene ring.
Keywords
Cyclohexanone , Cyclohexane , V2O5/Al2O3 , photocatalyst , Selective oxidation
Journal title
CATALYSIS TODAY
Serial Year
2004
Journal title
CATALYSIS TODAY
Record number
1232213
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