Title of article
Ionic liquid-derived zinc tetrahalide complexes: structure and application to the coupling reactions of alkylene oxides and CO2
Author/Authors
Jelliarko Palgunadi، نويسنده , , O-Sung Kwon، نويسنده , , Hyunjoo Lee، نويسنده , , Jin Yong Bae، نويسنده , , Byoung Sung Ahn، نويسنده , , Na-Young Min، نويسنده , , Hoon Sik Kim، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
511
To page
514
Abstract
Various alkylene carbonates have been prepared in high yields by the coupling reactions of alkylene oxides with CO2 in the presence of a dialkylimidazolium zinc tetrahalide complex, prepared from imidazolium halides and zinc halides. The single crystal X-ray diffraction analysis of an active species (1,3-dimethylimidazolium)2ZnBr2Cl2 showed that two 1,3-dimethylimidazolium cations were paired with a dibromodichloro zincate dianion.
Keywords
Imidazolium , Ionic liquid , Carbon dioxide , Zinc , Alkylene carbonate
Journal title
CATALYSIS TODAY
Serial Year
2004
Journal title
CATALYSIS TODAY
Record number
1234018
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