Aqueous tape casting and crystallization kinetics of Ce0.8La0.2O1.9 powder

An aqueous tape casting of Ce0.8La0.2O1.9 (LDC) ceramics was developed using PAA as dispersant, PVA as binder, PEG as plasticizer, and deionized water as solvent. Surface properties of LDC powder with and without PAA dispersant were characterized by electrokinetic measurements. The rheology of the LDC slurries was evaluated with a rotary viscometer. The zeta potential measurement showed that the isoelectric point for LDC powders in the absence of dispersant corresponds to a pH value of 4.02. The experimental results showed the pH value greatly affects the rheology of the slurry. The optimum content to get a stable dispersed slurry is 1.5 wt% PAA at pH value of 9–10. In presence of 1.5 wt% PAA dispersant, 5 wt% PVA binder, 5 wt% PEG plasticizer, and 55 wt% LDC powders exhibited shear thinning behavior, indicating that LDC slurry was homogenous and well stabilized. With an appropriate formulation homogeneous, smooth, and defect-free green tapes were successfully obtained. Moreover, the crystallization kinetics of LDC powders prepared by coprecipitation process also has been investigated in this study. The activation energy of crystallization was calculated on the basis of differential scanning calorimetry (DSC) at different heating rates. From non-isothermal DSC data presented values in the range of 343.3–379.1 kJ/mol and 2.282–2.030 for the activation energy of crystallization and the Avrami exponent, respectively, at specific temperatures ranging from 280 to 285 °C.