Interaction of the chromium–iron black pigment with porcelanised stoneware

A study has been undertaken on the interaction between the (Fe,Cr)2O3 black pigment and an industrial porcelanised stoneware composition at its firing temperature. The results indicate that the glassy phase that forms during firing preferentially extracts Fe2O3 from the pigment and probably contributes some Al2O3 to it, enriching the pigment composition in Cr2O3, without changing pigment crystal structure. The pigment alteration process mainly affects porcelanised stoneware microstructure and, to a lesser extent, color.