Title of article
Identification and synthesis of new bicyclic acetals from the mountain pine beetle, Dendroctonus ponderosae hopkins (Col.: Scol.) Original Research Article
Author/Authors
W. Francke، نويسنده , , F. Schr?der، نويسنده , , David P. Philipp، نويسنده , , H. Meyer، نويسنده , , V. Sinnwell، نويسنده , , G. Gries، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 1996
Pages
12
From page
363
To page
374
Abstract
Head-space volatiles obtained from male mountain pine beetles, Dendroctonus ponderosae, were analyzed by coupled GC-MS and chiral gas chromatography. 5-Ethyl-7-methyl-6,8-dioxabicyclo[3.2.1]octane (6) was found as a new naturally occurring isomer of brevicomin (1). In addition, several stereoisomers of 7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.1]octan-2-ol (11) and 1-(5-methyl-6,8-dioxabicyclo[3.2.1]octyl)ethanol (12) could be identified. Relative and absolute configurations of the compounds were determined by unambiguous syntheses, which are described.
Keywords
hydroxybrevicomin , Bicyclic acetals , Dendroctonus ponderosae , 5-ethyl-7-methyl-6
Journal title
Bioorganic and Medicinal Chemistry
Serial Year
1996
Journal title
Bioorganic and Medicinal Chemistry
Record number
1300660
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