Development of high temperature calorimeter: heat capacity measurement by direct heating pulse calorimetry Original Research Article

The temperature limit for heat capacity measurements with the direct heating pulse calorimeter has been increased up to 2000 K by means of the combination of an optical pyrometer to detect the relative temperature change with tungsten–rhenium thermocouples to determine absolute temperatures. With this improved calorimeter the heat capacities were measured up to 1950 K, for SiC and B4C, and 2000 K for graphite. The heat capacity values obtained in this study were in good agreement, within the error of ±5%, with those previous values calculated from the enthalpy data by drop method. The electrical conductivities of SiC, B4C and graphite were also simultaneously determined from the inducted voltage and the current for heat capacity measurement.