Preferential intercalation of isomeric but-2-enedioate anions into the layered double hydroxides Original Research Article

A power law used to describe the AC conductivity from 299 to 393 K of the mixed crystal (NH4)3H(SO4)1.42(SeO4)0.58 led to fractional exponent values ranging from 1.08 to 0.91, depending on structural changes induced on temperature variation [B. Louati, M. Gargouri, K. Guidara and T. Mhiri, J. Phys. Chem. Solids 66 (2005) 762]. In the present note, we suggest that the fractional law exhibits features of lattice relaxation. Despite the structural changes, the parameters of the power law are mutually interconnected to yield a temperature independent phenomenon. Such behavior is probably of general validity and characterizes the universal fractional dispersion of the AC conductivity, as it was also observed in glasses of different composition.