Title of article :
Study of surface-bulk mass transport and phase transformation in nano-TiO2 using hyperfine interaction technique Original Research Article
Author/Authors :
D. Banerjee، نويسنده , , S.K. Das، نويسنده , , S.V. Thakare، نويسنده , , P.Y. Nabhiraj، نويسنده , , R. Menon، نويسنده , , R.K. Bhandari، نويسنده , , K. Krishnan، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2010
Pages :
5
From page :
983
To page :
987
Abstract :
Phase transition from anatase to rutile for the 70 nm TiO2 crystallite has been investigated by the time differential perturbed angular correlation (TDPAC) technique. The study involved the annealing of the TiO2 nanocrystals, adsorbed with the nuclear probe (181Hf/181Ta) at trace level, at different temperatures for different durations. The TDPAC measurement was also supported by XRD measurement where the width of the peaks increases with the increase in annealing temperature indicating a crystal growth. The samples annealed up to 823 K for 4 h showed no phase transition, except for the growth of the crystallites. However, it showed phase transition at the same temperature (823 K), when annealed for longer duration, indicating the slower kinetics of the phase transition process. Further the sample, when annealed at 1123 K for 4 h, showed phase transition. It has also been observed that the 181Hf tracer, adsorbed on 70 nm anatase TiO2, diffuses from surface to bulk during the phase transition process and the extent of diffusion in anatase differs from that in rutile phase. However, surface to bulk mass-transfer is found to play a significant role in the phase transition process.
Keywords :
D. Phase transition , A. Oxide , D. Diffusion
Journal title :
Journal of Physics and Chemistry of Solids
Serial Year :
2010
Journal title :
Journal of Physics and Chemistry of Solids
Record number :
1311086
Link To Document :
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