Title of article
Novel ferrocene derived cyclocarbaphosphazenes: synthesis and structure of spiro {Fe(η-C5H5)-[η-C5H4CH2P(S)(CH2O)2PN]}(Me2NCN)2
Author/Authors
Dastagiri Reddy، Maliki Reddy نويسنده Sri Krishnadevaraya University, Anantapur, A.P., India. , , Anil J Elias، نويسنده , , Ashwani Vij، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
29
To page
31
Abstract
The first examples of ferrocene derived cyclocarbaphosphazenes have been synthesized by the reaction of Fe(η-C5H5)-[η-C5H4CH2P(S)(CH2OLi)2] with (RR′NCN)2(Cl2PN) [RR′N=Me2N and PhCH2(Me)N]. The crystal structure of the spirocyclic compound {Fe(η-C5H5)-[η-C5H4CH2P(S)(CH2O)2PN)]}(Me2NCN)2 has been determined and shows an axial orientation of the ferrocenylmethyl group with respect to the six-membered chair form of the spirocycle.
Keywords
spirocycle , Hydroxymethylferrocenes , Phosphine sulfide , Cyclocarbaphosphazene
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314797
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