Title of article :
Counter cation-controlled air oxidation of manganese derivatives of tetrachlorocatechol
Author/Authors :
Rafael Ruiz، نويسنده , , Andrea Caneschi، نويسنده , , Dante Gatteschi، نويسنده , , Claudio Sangregorio، نويسنده , , Lorenzo Sorace، نويسنده , , Miguel Vazquez، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)manganese(III) complex reacts with O2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding MnIV-tris(catecholate) species.
Keywords :
manganese , O–O activation , Oxygenation , Catecholato complexes , Hypervalent compounds , Potassium
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
