Title of article
Counter cation-controlled air oxidation of manganese derivatives of tetrachlorocatechol
Author/Authors
Rafael Ruiz، نويسنده , , Andrea Caneschi، نويسنده , , Dante Gatteschi، نويسنده , , Claudio Sangregorio، نويسنده , , Lorenzo Sorace، نويسنده , , Miguel Vazquez، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
4
From page
76
To page
79
Abstract
The potassium salt of the triphenylphosphine oxide adduct of bis(tetrachlorocatecholate)manganese(III) complex reacts with O2 in the presence of K+-sequestering agents at room temperature in MeCN resulting in the formation of the corresponding MnIV-tris(catecholate) species.
Keywords
manganese , O–O activation , Oxygenation , Catecholato complexes , Hypervalent compounds , Potassium
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314812
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