مرکز منطقه ای اطلاع رساني علوم و فناوري - Formation of diastereomeric clusters (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} in the reaction of diallylsulfide with (μ-H)2Os3(CO)10

Title of article :

Formation of diastereomeric clusters (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} in the reaction of diallylsulfide with (μ-H)2Os3(CO)10

Author/Authors :

Vladimir P Kirin، نويسنده , , Vladimir A Maksakov، نويسنده , , Alexander V Virovets، نويسنده , , Anatoliy V Golovin، نويسنده ,

Issue Information :

روزنامه با شماره پیاپی سال 2000

Pages :

From page :

224

To page :

226

Abstract :

The interaction of (μ-H)2Os3(CO)10 with diallylsulfide S(Allyl)2 results in the formation of (μ-H)Os3(CO)10{μ, η2 (S,C)-S(Allyl)CHCH2CH3} (two diastereomers, 2a,b) and Os3(CO)10{η3(S,C,C)-S(Allyl)CH2CHCH2}. The crystal and molecular structures of 2a have been determined by X-ray analysis.

Keywords :

Diastereomers , crystal structures , Triosmium clusters , Allylsulfide complexes , Cluster complexes , Osmium complexes , Hydrogenation , Isomerization

Journal title :

Inorganic Chemistry Communications

Serial Year :

2000

Journal title :

Inorganic Chemistry Communications

Record number :

1314854

Link To Document :

https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1314854