Title of article :
A cyanohydridoborato–vanadium(II) complex, trans-[V(NCBH3)2(thf)4]
Author/Authors :
Ronald Hedelt، نويسنده , , Carola Schulzke، نويسنده , , Dieter Rehder، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
[V(NCBH3)2(thf)4], the first cyanohydroborato complex of an early transition metal, has been generated in the system [V(CO)6]−/I2/tolane/Na[NCBH3] in THF. The crystal structure reveals an ideal trans configuration (point group D2h) with about linear CNBH3− units, and without intermolecular (hydrogen bonding) interactions.
Keywords :
Cyanohydroborato complexes , Vanadium complexes , Tetrahydrofurane complexes , crystal structures
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
