Title of article
Synthesis and structure of {η3-MeSi(CH2SPh)3}Cr(CO)3: how long can a Cr(0)–S(thioether) bond length be?
Author/Authors
William C. Blackwell III، نويسنده , , Dmitry Bunich، نويسنده , , Thomas E. Concolino، نويسنده , , Arnold L. Rheingold، نويسنده , , Daniel Rabinovich، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
3
From page
325
To page
327
Abstract
The new tridentate thioether ligand MeSi(CH2SPh)3 has been prepared in good yield and its first transition metal derivative, the octahedral chromium tricarbonyl complex {η3-MeSi(CH2SPh)3}Cr(CO)3, has been synthesized and fully characterized. In agreement with the reduced basicity of arylthioethers and the expected lability of their metal complexes, the new complex exhibits the longest Cr(0)–S(thioether) bond distances observed to date.
Keywords
Thioether complexes , chromium complexes , Tris(thioether)silane , crystal structures
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314881
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