Title of article
A novel dimer of oxo-di(acetato)-bridged manganese(III) dimers complex of potential biological significance
Author/Authors
Rafael Ruiz، نويسنده , , Claudio Sangregorio، نويسنده , , Andrea Caneschi، نويسنده , , Patrizia Rossi، نويسنده , , Ana B Gaspar، نويسنده , , Jose A Real، نويسنده , , M.Carmen Mu?oz، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2000
Pages
7
From page
361
To page
367
Abstract
Assembly of the tetranuclear oxomanganese(III) acetato cluster [Mn4O2(O2CMe)7(phen)2](BF4) from the dinuclear oxo-di(acetato)-bridged manganese(III) species [Mn2O(O2CMe)2(H2O)2(phen)2](BF4)2·3H2O in aqueous/acetic acid MeOH solution occurs via the new ‘dimer of dimers’ MnIII complex [Mn2O(O2CMe)3(H2O)(phen)2](BF4)·MeOH possesing an unprecedent [Mn4(μ-O)2(μ-O2CMe)4(μ-OH2…O2CMe)2] core.
Keywords
Cluster compounds , Carboxylato complexes , manganese , N ligands , O ligands , crystal structures
Journal title
Inorganic Chemistry Communications
Serial Year
2000
Journal title
Inorganic Chemistry Communications
Record number
1314890
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