Title of article :
The carbonylation of methylacetate to acetic anhydride catalysed by [Cp∗Rh(CO)2] in the absence of hydrogen
Author/Authors :
Andrew C. Marr، نويسنده , , Philip Lightfoot، نويسنده , , Evert J. Ditzel، نويسنده , , Andrew D. Poole، نويسنده , , Gary P. Schwarz، نويسنده , , Douglas F. Foster، نويسنده , , David J. Cole-Hamilton، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2000
Abstract :
[Cp∗Rh(CO)2] catalyses the carbonylation of methylacetate to acetic anhydride at 6.9 mol dm3 h−1 in the absence of hydrogen; [Cp∗RhI2(CO)] which forms from it is also catalytically active giving rates of 1.2 mol dm3 h−1 under the same conditions.
Keywords :
Pentamethylcyclopentadienyl , WGSR , Methyl acetate , Carbonylation , Acetic anhydride , Rhodium
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
