• Title of article

    Dirhodium(II) carboxylate complexes as building blocks. Synthesis of dimeric species as connectors for macrocycles

  • Author/Authors

    Richard P. Bonar-Law، نويسنده , , Thomas D. McGrath، نويسنده , , Jamie F. Bickley، نويسنده , , Cristina Femoni، نويسنده , , Alexander Steiner، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    16
  • To page
    18
  • Abstract
    Two complexes of the form (AcO)2Rh2LRh2(OAc)2 in which two Rh24+ units are covalently linked have been prepared by reaction of Rh2(OAc)4 with bischelating tetracarboxylate ligand L=(−O2CC(Me)2O))2PhPh(OC(CH3)2CO2−)2 in N,N-dimethylaniline. A crystal structure of the major (kinetic) product showed, unexpectedly, that it contained two 14 membered chelate rings, with the isomeric minor (thermodynamic) product having two 12 membered chelate rings.
  • Keywords
    Dirhodium tetracarboxylates , Chelates , crystal structure , Dimers , Macrocycles
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2001
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1314983

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1314983