Title of article :
Synthesis and crystal structure of trans-nitrosoaquatetraammineruthenium(II) sulphate hydrosulphate, [Ru(NO)(NH3)4(H2O)](SO4)(HSO4)
Author/Authors :
V.A. Emelʹyanov، نويسنده , , A.V Virovets، نويسنده , , I.A. Baidina، نويسنده , , S.A. Gromilov، نويسنده , , A.V. Belyaev، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
The reaction between [RuNO(NH3)4OH]Cl2 and an excess of 2 M H2SO4 leads to the protonation of the starting complex and crystallisation of the title complex with sulphate and hydrosulphate anions. The crystal structure of the product has been determined. The linear nitroso group and water molecule are coordinated in trans positions.
Keywords :
Ammine complex , Nitroso complex , crystal structure , Sulphate , Ruthenium(II)
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications