Title of article :
Titanium(IV) complexes of trianionic amine triphenolate ligands
Author/Authors :
Moshe Kol، نويسنده , , Marina Shamis، نويسنده , , Israel Goldberg، نويسنده , , Zeev Goldschmidt، نويسنده , , Sima Alfi، نويسنده , , Einat Hayut-Salant، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
Two trianionic amine triphenolate ligands are introduced and their isopropoxide Ti(IV) complexes synthesized. The two complexes are mononuclear and C3-symmetrical on the NMR timescale. High barriers to inversion (ΔG‡>65 KJ mol−1) between the enantiomers of each complex were found. The complex derived from the bulkier tripodal ligand shows a better resistance to hydrolysis.
Keywords :
Tripodal ligands , Phenolate ligands , titanium complexes , X-ray structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
