Title of article :
Nickel(II) promoted P–N bond cleavage of (Ph2PNH)2CS. X-ray crystal structure of trans-[Ni{Ph2PNHC(S)NH2– P,S}2]Cl2
Author/Authors :
Pravat Bhattacharyya، نويسنده , , Alexandra M.Z Slawin، نويسنده , , J. Derek Woollins، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
The reaction of (Ph2PNH)2CS with nickel(II) chloride hexahydrate in methanol proceeds with methanolysis of a P–N bond to give trans-[Ni{Ph2PNHC(S)NH2–P,S}2]Cl2, whose structure has been confirmed by X-ray crystallography.
Keywords :
nickel , Phosphine , P–N bond , X-ray crystal structure
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
