• Title of article

    Photoreduction of aqueous ferrioxamine B by oxalate induced by outer-sphere charge transfer excitation

  • Author/Authors

    Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    215
  • To page
    217
  • Abstract
    The Fe(III) siderophore cation [ferrioxamine B]+ and oxalate form an ion pair which shows an outer-sphere charge transfer (OSCT) absorption at λmax=262 nm. While ferrioxamine B is not light-sensitive the aqueous ion pair [ferrioxamine B]+C2O42− undergoes a photoreduction to Fe(II) upon OSCT excitation.
  • Keywords
    Charge transfer , Electronic spectra , Photochemistry , siderophores , Iron complexes
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2001
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315035

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1315035