Title of article :
Deprotonation of a ruthenium (II) complex incorporating a bipyrazole ligand leading to optical and electrochemical switching
Author/Authors :
Huw Jones، نويسنده , , Mike Newell، نويسنده , , Clive Metcalfe، نويسنده , , Sharon E. Spey، نويسنده , , Harry Adams، نويسنده , , Jim A. Thomas، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
The synthesis of a Ru(II) complex incorporating the 3,3′-bipyrazole (bpyz) ligand is reported. Deprotonation of the ligand leads to shifts in both the metal-to-ligand charge transfer (MLCT) band (80 nm) and the RuIII/II oxidation couple (>750 mV) of the complex.
Keywords :
crystal structure , Bipyrazole complex , Molecular devices , Ruthenium complex
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
