Title of article
Synthesis and crystal structure of a novel vanadium-containing tungstobismutate(III) K12[(VO)3(BiW9O33)2]·30H2O
Author/Authors
Bogdan Botar، نويسنده , , Toshihiro Yamase، نويسنده , , Eri Ishikawa، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
4
From page
551
To page
554
Abstract
The tris(vanadyl)-substituted tungstobismutate(III) [(VO)3(BiW9O33)2]12− anion has been synthesized by reaction of α-B[BiW9O33]9− with VOSO4 in aqueous solution. The anion is made of two α-B[BiW9O33]9− units linked by a belt of three exterior VO2+ groups into an assembly of virtual D3h symmetry. The three vanadium centers are well separated by a V⋯V distance of 5.375(4)–5.474(4) Å.
Keywords
crystal structure , ?-B tungstobismutate , V/W/Bi-mixed polyanion , Tris(vanadyl)-substituted tungstobismutate(III)
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315166
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