Title of article :
A 3D Keggin-based framework containing AgI-ribbons and cycles by using rigid tetrazole-based ligand
Author/Authors :
Aixiang Tian، نويسنده , , Xiaoling Lin، نويسنده , , Na Sun، نويسنده , , Jun Ying، نويسنده , , Juwen Zhang، نويسنده , , Na Li، نويسنده , , Xiuli Wang، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
A new Keggin-type polyoxometalate (POM)-based compound, [Ag9(ptz)5][PMoVI11MoVO40]·H2O (1) (ptzH = 5-phenyl-1H-tetrazole), was synthesized under hydrothermal conditions. Compound 1 exhibits a 2D layer containing AgI ribbons and hexa-nuclear AgI circles, which are further linked by AgI atoms and [PMoVI11MoVO40]4 − anions to construct a 3D framework. The electrochemical properties of compound 1 have been investigated.
Keywords :
Rigid ptz ligand , Electrochemical property , Keggin polyoxometalate , Hydrothermal synthesis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications