• Title of article

    The first octanuclear tin(IV)–oxosulfide cluster

  • Author/Authors

    Liming Wu، نويسنده , , Ling Chen، نويسنده , , Jingcao Dai، نويسنده , , Chuanpeng Cui، نويسنده , , Zhiyong Fu، نويسنده , , Xintao Wu، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2001
  • Pages
    3
  • From page
    574
  • To page
    576
  • Abstract
    The first octanuclear tin(IV)–oxosulfide complex (NH4)2(Et4N)4[Sn8S12O4(SPh)6] has been synthesized by mixing stoichiometric amount of Sn(SPh)4 and (NH4)2WOS3 and thiophenol in DMF. The compound was crystallized in orthorhombic space group Cmcm, Z=4, a=18.0463(4) Å, b=15.7599(2) Å, c=19.1914(5) Å, a single crystal X-ray diffraction analysis revealed two coordinate modes of the tin atoms: five-coordinated distorted rectangular pyramid SnOS4 and six-coordinated octahedron SnO3S3.
  • Keywords
    Thiophenol , Tin(IV)–oxosulfide complex , DMF , crystal structures
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2001
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315175

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1315175