Title of article :
Solvent-induced supramolecular isomerism in homochiral silver benzimidazolates
Author/Authors :
Xun-Gao Liu، نويسنده , , Yanying Wang، نويسنده , , Yingying Hu a، نويسنده , , Zhi-Guo Gu، نويسنده , , Liang Shen، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
Two pairs of enantiomers R-[Ag4(hebim)4] · 3DMAC (R-1), S-[Ag4(hebim)4] · 3DMAC (S-1), R-[Ag(hebim)] (R-2) and S-[Ag(hebim)] (S-2) [Hhebim = 2-(1-hydroxyethyl) benzimidazole] are reported. Complexes 1 and 2 are supramolecular isomers induced by solvent and are second harmonic generation (SHG) active. In addition, solid-state luminescent properties of 1 and 2 were investigated at room temperature.
Keywords :
Second harmonic generation , Supramolecular isomerism , Luminescence , Ag(I)
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
