Title of article
Photooxidation of N,N′-bis(3,5-di-tert.-butylsalicylidene)-1,2-diamino hexane-manganese(III) chloride (Jacobsen catalyst) in chloroform
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
3
From page
692
To page
694
Abstract
MnIII(J-salen)Cl (Jacobsen catalyst) with J-salen=N,N′-bis(3,5-di-tert.-butylsalicylidene)-1,2-diaminocyclohexane dianion in CHCl3 is photooxidized by the solvent to a MnIV(J-salen) complex, presumably MnIV(J-salen)Cl2, with φ=0.002 at λirr=333 nm.
Keywords
Photochemistry , Salen complexes , Manganese complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2001
Journal title
Inorganic Chemistry Communications
Record number
1315219
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