Title of article :
Synthesis and structural characterization of new one-dimensional rhodium complexes
Author/Authors :
Florian P. Pruchnik، نويسنده , , Piotr Jakimowicz، نويسنده , , Zbigniew Ciunik، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2001
Abstract :
New one-dimensional RhI–RhII complexes [Rh2(OOCMe)2(phen)2]n(PF6)n·0.5nMe2CHOH, 1 and [Rh2(OOCMe)2(bpy)2]n(PF6)n·nH2O, 2 have been synthesized and characterized. The compound 1 is molecular wire with the shortest Rh(I)–Rh(II) distances, anions and solvate molecules occupy channels between parallel cationic wires.
Keywords :
Nitrogen heterocycles , N ligands , Stacking interactions , Rhodium , Metal wires
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
