Title of article :
Regioselective olefin arylation catalyzed by [Ir(acac)2Cl]2 with base
Author/Authors :
Takaya Matsumoto، نويسنده , , Hajime Yoshida، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
By addition of bases to remove Cl in situ, [Ir(acac)2Cl]2 was found to work as a catalyst for anti-Markovnikov arylation of olefin with benzene to produce straight-chain alkylbenzene in higher selectivity than the branched alkylbenzene the same as [Ir(acac)3]2.
Keywords :
Iridium complex , Anti-Markovnikov , C–H bond activation , arylation , Regioselectivity , Homogeneous catalysis
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications