Title of article :
Synthesis, characterization and reactivity of a novel Di-nickel complex towards carbon dioxide
Author/Authors :
William Seals، نويسنده , , Hadi Arman، نويسنده , , Stephan B.H. Bach، نويسنده , , Ghezai T. Musie، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
Newly synthesized dinickel complex 1, K2[Ni2(ccdp)(C5H7O2)(H2O)2], reacts with CO2 to produce a novel bis(μ-η2,η2)-carbonato bridged tetranickel complex 2, Cs6[Ni4(ccdp)2(μ-η2-η2-CO3)2], via an intermediate species that contains a bis(μ-OH) dinickel(II) moiety, complex 3.
Keywords :
Metal complex activation , Nickel complex , Carbonato ligand , Carbon dioxide
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
