Title of article :
Two structurally different praseodymium-organic frameworks with permanent porosity
Author/Authors :
Osamah Alduhaish، نويسنده , , Bin Li، نويسنده , , Vladimir Nesterov، نويسنده , , Hadi D. Arman، نويسنده , , Khalid Alfooty، نويسنده , , Abdullah M. Asiri، نويسنده , , Hailong Wang، نويسنده , , Banglin Chen، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2014
Abstract :
Two Praseodymium-organic frameworks, [Pr2(NDC)2(NO3)2(DMA)4] (1) and [Pr3(NDC)4.5(DMF)3(H2O)] (2) (H2NDC = 2,6-naphthalenedicarboxylic acid; DMA = N,N-dimethylacetamide; DMF = N,N-dimethylformamide) have been synthesized and structurally characterized. The discrete Pr2(COO)4 cluster and 1D [Pr(COO)3]n rod act as the secondary building units in MOF 1 and MOF 2, respectively, leading to their different structures of 2D sheet and 3D rod-packing. Their permanent porosities have been also established.
Keywords :
Metal-organic framework , Porous material , Lanthanide-organic framework , crystal structure , Gas sorption
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
