Title of article
Preparation and structural characterisation of a novel palladium (II) binuclear complex containing triazole bisthiosemicarbazone bridges
Author/Authors
Pilar Souza، نويسنده , , Ana I. Matesanz، نويسنده , , César Pastor، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
3
From page
344
To page
346
Abstract
A new polidentate ligand, 3,5-diacyl-1,2,4-triazolebis(4-methylthiosemicarbazone), (H5L) has been synthesised; complexation of this ligand with Li2PdCl4 leads to a novel stable [Pd2(μ-H3L)2] macrocyclic cage which was characterised by X-ray crystallography. The ligand coordinates to the Pd atoms in a new tridentate fashion, forming a chelating and a bridging bonding modes.
Keywords
crystal structure , 2 , 4-Triazoles , 1 , Palladium(II) complexes , Bis(thiosemicarbazone)
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315567
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