Title of article
Convenient one-pot synthesis of triphenylphosphinecarbomethoxyborane: antitumor activity and structural investigation
Author/Authors
Kamesh Vyakaranam، نويسنده , , Geeta Rana، نويسنده , , Shoujian Li، نويسنده , , Chong Zheng، نويسنده , , Bernard F. Spielvogel، نويسنده , , John A. Maguire، نويسنده , , Narayan S. Hosmane، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
3
From page
458
To page
460
Abstract
The reaction of equimolar quantities of trimethylaminecarbomethoxyborane and triphenylphosphine, in anhydrous 1, 2-dimethoxyethane (monoglyme), produced triphenylphosphinecarbomethoxyborane in 63% yield, via a Lewis-base exchange reaction. The structure of 1 unambiguously shows that the triphenylphosphine moiety coordinates to the boron atom with the C(O)OCH3 group intact.
Keywords
Lewis-base exchange reaction , Substituted borane adducts , antineoplastic , Boron biomolecules , BNCT
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315600
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