Title of article
The anion [AsIII5MoVI4O20(OCH3)]2−: a new heteropolyoxometalate containing an unusual As5O4 chain
Author/Authors
Myriam Laly، نويسنده , , Eva Garcia Fidalgo، نويسنده , , Helen Stoeckli-Evans، نويسنده , , Georg Süss-Fink، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
3
From page
569
To page
571
Abstract
The heteropolyoxometalate [HAsIIIAsVMoVMoVI8O34]6− reacts in aqueous solution with an excess of sodium metaarsenite to give a new arsenomolybdate [AsIII5MoVI4O20(OCH3)]2− which crystallize as the tetrabutylammonium salt. The single-crystal X-ray structure analysis reveals a heteropolyoxometalate anion containing an unusual chain of five arsenic atoms linked to each other by bridging oxygen atoms.
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315627
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