Title of article
Oligocyanometallic cords as building blocks in luminescent three-dimensional coordination polymers: [Ag4Cd2(tren)2(CN)6.5][Ag(CN)1.5] and [Au2Cd(tren)(CN)4]·H2O
Author/Authors
Hao Zhang، نويسنده , , Jiwen Cai، نويسنده , , Xiao-Long Feng، نويسنده , , Tao Li، نويسنده , , Xiao-Yuan Li، نويسنده , , Liang-Nian Ji، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
5
From page
637
To page
641
Abstract
The syntheses, structures and luminescent properties of two unusual mixed-metal coordination polymers, namely [Ag4Cd2(tren)2(CN)7.5][Ag(CN)1.5] 1 and [Au2Cd(tren)(CN)4]·H2O 2 (tren = tris(2-aminoethyl)amine), are presented. Both compounds contain abnormal metal cords of oligocyanometallic anions as building blocks wherein the d10–d10 interaction plays a crucial role in the metal–metal assembly.
Keywords
Coordination polymers , cyano , Luminescent emission , Coinage metal
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315649
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