Title of article :
A new porous 2D copper(II) metal–organic framework for selective adsorption of CO2 over N2
Author/Authors :
Da-Shu Chen، نويسنده , , Jia-Ming Cheng، نويسنده , , Li-Bo Sun، نويسنده , , Zhiqiang Liang، نويسنده , , Kui-Zhan Shao، نويسنده , , Chungang Wang، نويسنده , , Hong-Zhu Xing، نويسنده , , Zhongmin Su، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2013
Abstract :
A new porous 2D metal–organic framework [Cu(L)DMF]·2H2O (1) has been synthesized by self-assembling copper paddle-wheel units with an asymmetrical dicarboxylate ligand prolonged by alkyne groups, 3,3′-(ethyne-1,2-diyl)dibenzoic acid (H2L) under solvothermal condition. The activated sample 1a displays selective adsorption of CO2 over N2 and shows low isosteric heat (Qst) of CO2 adsorption.
Keywords :
Metal–organic frameworks , Asymmetrical ligand , Adsorption , Microporous , CO2
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
