Title of article :
Half-sandwich ruthenium complexes for the controlled radical polymerisation of vinyl monomers
Author/Authors :
Oscar Tutusaus، نويسنده , , Sébastien Delfosse، نويسنده , , François Simal، نويسنده , , Albert Demonceau، نويسنده , , Alfred F. Noels، نويسنده , , Rosario N??ez، نويسنده , , Clara Vi?as، نويسنده , , Francesc Teixidor، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
Ruthenium complexes of the type [RuX(Cp#)(PPh3)2] (X=Cl and H; Cp#=Cp, Cp*, indenyl, and carboranyl) catalyse the radical polymerisation of styrene and n-butyl acrylate, and both the catalyst activity and the degree of control of the polymerisation strongly depend on the Cp# ligand and the monomer.
Keywords :
olefins , Homogeneous catalysis , ruthenium and compounds , Polymerisations , Radical reactions
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
