Title of article :
Synthesis and X-ray single crystal study of Co2Al2(OiPr)6(acac)4—first representative of a new structure type for the heterometallic alkoxide complexes
Author/Authors :
Evgeniya Suslova، نويسنده , , Gulaim A. Seisenbaeva، نويسنده , , Vadim G. Kessler، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2002
Abstract :
The interaction of Co(acac)2with Al(OiPr)3in 1:1 ratio in toluene on reflux provided with quantitative yield a new heterometallic heteroleptic alkoxide complex, Co2Al2(OiPr)6(acac)4(I), displaying the so far unprecedented linear chain structure with a M′(μ-OR)2M(μ-OR)2M(μ-OR)2M′core. I appears to be a promising precursor for cobalt oxide–cobalt spinel nanocomposite materials.
Keywords :
Alkoxoaluminates , Heterometallic alkoxides , Co spinel , X-ray study , Late transition metal alkoxides
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
