• Title of article

    The first one-dimensional heteropoly tungstovanadate coordination polymer: [(VVO4)WVI8M4O36(VIVO)2]n− (M=0.71VIV+0.29WVI, n=4.68)

  • Author/Authors

    Vaddypally Shivaiah and Samar K. Das، نويسنده , , Swapna Hajeebu، نويسنده , , Samar K. Das، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2002
  • Pages
    4
  • From page
    996
  • To page
    999
  • Abstract
    An aqueous ammonium acetate buffer solution (pH 4) containing vanadate, tungstate and dithionite ions, on heating at 100 °C for 1 h yields one-dimensional polyoxometalate chain compound (NH4)4.68[(VVO4)WVI8M4O36(VIVO)2]·12H2O (M=0.71VIV+0.29WVI) 1, which is characterized by single-crystal X-ray structure determination, redox titration, and IR spectroscopic studies. Crystallographic data for 1, H42.72N4.68O54V5.84W9.16, tetragonal, space group I 4̄, a=15.8132(5), c=11.1114(5) Å, Z=2, V=2778.5(2) Å3.
  • Keywords
    Reduction , Polyoxometalate , One-dimensional chain , Tungstovanadate heteropoly complex
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2002
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315872

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1315872