Title of article
Stepwise synthesis of a pentanuclear copper(II)–manganese(II) cluster by using a versatile Schiff base ligand derived from 3-formylsalicylic acid
Author/Authors
Floriana Tuna، نويسنده , , Luminita Patron، نويسنده , , Marius Andruh، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
30
To page
33
Abstract
The Schiff base 3-[N-2-(pyridylethyl)formimidoyl]salicylic acid (H2L) is a useful ligand for the design of heteronuclear complexes. A pentanuclear copper(II)–manganese(II) cluster was synthesized by using H2L as a ligand. The compound was characterised by analytical and spectral methods. Cryomagnetic investigations over the temperature range 1.9–300 K reveal antiferromagnetic interactions between the copper(II) and manganese(II) ions.
Keywords
Copper(II) complexes , Binucleating ligands , Manganese(II) complexes , Magnetic properties , Schiff bases
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1315905
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