• Title of article

    Bisphosphino ureas: flexible ligands with rigid backbone

  • Author/Authors

    Olaf Kühl، نويسنده , , Walter Langel، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    74
  • To page
    77
  • Abstract
    The nickel(0) complex [Ni{η2-(PPh2NMe)2CO}{η1-(PPh2NMe)2CO}] 1 was obtained by the reaction of NiCl2·6H2O with two equivalents of the ligand (PPh2NMe)2CO in the presence of zinc as reducing agent. The structure of 1 was unambiguously determined by 1H and 31P–{1H} NMR spectroscopy and compared to the known structures of the extremely strained Pd(II) and Mo(0) complexes of (PPh2NMe)2CO.
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2003
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315916