Title of article :
A novel heterometallic μ4-oxo-bridged complex based on an octahedral Cd2Cu4 skeleton via the reaction of elemental copper, cadmium acetate and amino alcohol
Author/Authors :
Elena A. Vinogradova، نويسنده , , Vladimir N. Kokozay، نويسنده , , Olga Yu. Vassilyeva، نويسنده , , Brian W. Skelton، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The reaction of copper powder in dmso with cadmium acetate hydrate and 2-dimethylaminoethanol (HL), in open air, afforded [Cd2Cu4(μ4-O)(O2CMe)6L4]·2H2O with a metal skeleton that approximates an octahedron. The copper atoms are tetrahedrally arranged about the oxygen atom in a considerably distorted fashion. The amino alkoxo and acetate ligands display a variety of bonding modes in the complex.
Keywords :
2-Dimethylaminoethanol , crystal structure , ?4-Bridging oxygen , Zero-valent copper , Heterometallic complex
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
