Title of article :
Reactions of cyclic and linear alkynols with a phosphinic iron(II) centre
Author/Authors :
Ana I.F. Venâncio، نويسنده , , Lu??sa M.D.R.S. Martins، نويسنده , , Jo?o J.R. Fra?sto da Silva، نويسنده , , Armando J.L. Pombeiro، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
Treatment of a MeOH solution of trans-[FeBr2(depe)2] (depe=Et2PCH2CH2PEt2) with HCCC6H10OH or HCC(CH2)nOH (n=1 or 2), in the presence of NaBPh4, forms the cyclic allenylidene trans-[FeBr(CCC6H10)(depe)2][BPh4] or the alkyne trans-[FeBr{η2-HCC(CH2)nOH}(depe)2][BPh4] (n=1 or 2) complexes, respectively.
Keywords :
Iron , Propargyl alcohols , alkynes , Phosphinic complexes , alkynols , Allenylidenes
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications