Title of article :
μ3-SH dicapped triangular copper(I) complex of bis(diphenylphosphino)amine
Author/Authors :
Lei Han، نويسنده , , Lin-Xi Shi، نويسنده , , Li-Yi Zhang، نويسنده , , Zhong-Ning Chen، نويسنده , , Mao-Chun Hong، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The reaction between [Cu2(Ph2PNHPPh2)2(MeCN)2](BF4)2 and sodium salt of mercaptoacetic acid (HSCH2COONa) at room temperature for 12 h produced a doubly μ3-SH-bridged tricopper complex [Cu3(μ-Ph2PNHPPh2)3(μ3-SH)2](BF4)·2MeOH·Et2O which affords a trigonal bipyramidal core of Cu3(μ3-SH)2 with copper ⋯ copper separations around 3.0 Å. The complex is photoluminescent and it displays an emissive maximum at 523 nm in the solid state at 293 K.
Keywords :
Sulfhydryl , Trinuclear , Bis(diphenylphosphino)amine , Copper(I)
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
