Title of article
A new lead(II) inorganic–organic hybrid of the P,P′-diphenylmethylene-diphosphinate ligand: synthesis and X-ray characterization of the [Pb(CH2(P(Ph)O2)2)] complex
Author/Authors
Franco Cecconi، نويسنده , , Carlo A. Ghilardi، نويسنده , , Stefano Midollini، نويسنده , , Annabella Orlandini، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
3
From page
546
To page
548
Abstract
By reaction of lead(II) nitrate with P,P′-diphenylmethylenediphosphinic acid in water solution a new inorganic–organic hybrid of formula [Pb(CH2(P(Ph)O2)2)] has been synthesized and structurally characterized. The complex displays a polymeric columnar structure, the column being formed by two intersecting sinusoidal ribbons of lead(II) ions bridged by bifunctional phosphinate ligands. The intersections of the ribbons are constituted by dimeric units of pentacoordinated lead(II) ions.
Keywords
Inorganic–organic hybrids , crystal structures , Polymeric complexes , Lead complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316027
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