Title of article :
A novel cyano-bridged Sr(II)–Fe(III) polymer containing alternating octanuclear and tetranuclear cores
Author/Authors :
Amitabha Datta، نويسنده , , G.M. Golzar Hossain، نويسنده , , Nirmal Kumar Karan، نويسنده , , K.M. Abdul Malik، نويسنده , , Samiran Mitra، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
A novel cyano-bridged Sr(II)–Fe(III) polymeric complex ([Sr3(phen)6(H2O)6{Fe(CN)6}2]·phen·6.5H2O)n (1) has been synthesized and structurally characterized. The complex contains alternating octanuclear 24-membered and tetranuclear 12-membered metallocycles, which are repeated to form a polymeric chain. The Sr(II) centres are eight coordinated with distorted bicapped trigonal prismatic geometry while the Fe(III) centres have six coordinate octahedral geometry.
Keywords :
crystal structure , Cyano-bridged , Strontium–iron , Phenanthroline , Heterometallic macrocycle
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
