• Title of article

    The synthesis of (η5-cyclopentadienyl)titanium(IV) alkoxides by alcoholysis of the Ti–π-ligand bond in permethyl η3:η4-allyldiene-(η5-cyclopentadienyl)titanium(II)

  • Author/Authors

    Karel Mach، نويسنده , , Ji??? Kubi?ta، نويسنده , , Libor Trojan، نويسنده , , Ivana Cisarova، نويسنده , , Petr ?t?pni?ka، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    974
  • To page
    977
  • Abstract
    The η3:η4-allyldiene-(η5-cyclopentadienyl)titanium(II) complex [Ti(η5-C5Me5){η3:η4-C5Me3(CH2)2}] (1) reacts with three molar equivalents of substituted propargylic alcohols FcCCCMe2(OH) (2a) and PhCCCH2OH (2b) at elevated temperature to give (η5-pentamethylcyclopentadienyl)titanium(IV) alkoxides [Ti(η5-C5Me5)(FcCCCMe2O-κO)3] (3a) and [Ti(η5-C5Me5)(PhCCCH2O-κO)3] (3b), respectively. The crystal structure of 3a has been determined by single-crystal X-ray diffraction.
  • Keywords
    Titanium , Cyclopentadienyl , Ferrocene , alkyne , Alkoxide , X-ray crystallography
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2003
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1316130

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1316130