Title of article :
A transition metal complex containing pyrazine-2,5-dicarboxylato bridging ligands: a novel three-dimensional manganese(II) compound
Author/Authors :
Garikoitz Beobide، نويسنده , , Oscar Castillo، نويسنده , , Antonio Luque، نويسنده , , Urko Garc??a-Couceiro، نويسنده , , Juan P. Garc??a-Teran، نويسنده , , Pascual Rom?n، نويسنده , , Luis Lezama، نويسنده ,
Issue Information :
روزنامه با شماره پیاپی سال 2003
Abstract :
The novel metal-organic polymer [Mn(μ4-pzdc)]n (H2pzdc=pyrazine-2,5-dicarboxylic acid) has been synthesized by the hydrothermal reaction of Mn(NO3)2 · 4H2O with H2pzdc. X-ray diffraction analysis shows that the polymer exhibits an extended three-dimensional network with hexadentated pzdc ligands bridging four manganese(II) atoms. The magnetic measurements show the occurrence of weak antiferromagnetic couplings.
Keywords :
Pyrazine bridge , Three-dimensional complex , dicarboxylate , crystal structure , Magnetic properties , Manganese complex
Journal title :
Inorganic Chemistry Communications
Journal title :
Inorganic Chemistry Communications
