Title of article
Photoredox reactivity of iron(III) phenolates in aqueous solution induced by ligand-to-metal charge transfer excitation
Author/Authors
Horst Kunkely، نويسنده , , Arnd Vogler، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
3
From page
1335
To page
1337
Abstract
Iron(III) complexes with phenolate ligands (m-cresolate and tyrosinate) undergo a redox photolysis in aqueous solution upon phenolate → Fe(III) ligand-to-metal charge transfer excitation. At λirr=577 nm the quantum yields of Fe(II) formation are approximately φ=10−4.
Keywords
Charge transfer , Photochemistry , Electronic spectra , Iron complexes , Phenol , Tyrosine
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316219
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